Welcome to pherotalk! 
Well, no phero will force anyone out of their comfort zone to do anything they are not already substantially inclined to do. However, when combined with the right situation and the right behaviours/body language etc, they can help add that final little push in your direction if they are thinking on it. 
As to what pheros/combinations, that depends a lot on the situation - Strong/overt none (eg TUTH) is best kept for the most sexually charged and uninhibited situations like parties and when close to the bedroom with someone. A more balanced product like Ammo can be worn in a much wider range of situations, like work, class and more general socialising but still give a sexy/interesting/alluring and confident vibe without the risk of creeping-out or triggering aggressive behaviour.
The Socials are also very useful here - both to take the raw edge off the none and to add-in layers that promote other feelings which help steer the responses the way you want them:
Instant Shine - gives a happy/feelgood/socially confident impression that goes really well with Ammo.
IO - Helps promote easy/flowing conversation. Great for breaking the ice.
IH - Helps inspire quality conversation and deepen bonding/trust between people.
IG - Gives a smooth suave status impression that will sit well with someone your age.
These threads are worth a look - covers the basics of phero use: