Welcome to Pherotalk whoadude!,
“I’m not terribly sure of what I should be doing right now, with regards to pheromones, so I thought this website would offer some help.”
You picked the right place 
“I thought maybe I would try a handful of the to-go bottles just as a test for some different situations”
good idea
The situation you mentioned(“friendzone”) is not new to this forum so you will find a lot of people who have been in the same or are working to get out of that situation daily and they can help you along. You might want to look at ITNerd’s journal and the thread “Friend zone? IJ and TUTH are your friend zone busters.”
Looks like you have already done some research.
My suggestions would be:
Instant Shine: this makes you and the people around you feel good/happy. I like this one because people like to be around happy people.
And
Ammunition: This is a social/sexy product used for attraction.