Hello BigTrev!
Welcome to PheromoneTalk!
For a beginner, I will recommend the Ultimate Pheromone Intro Pack for you. It contains every bestselling pheromone for men in small ToGo sizes, giving you an opportunity to own each type and test, and thus understand its different self and social effects. 
Here’s a thread that will be of help in case you’ll gonna end up with UPIP.
It would be of great delight if I can give you a $25 free coupon to help cushion your first order, but I can’t. 
Your initial post seems not enough to pull my finger-trigger.
But if you are still interested, “just tell us a bit about yourself (age, sex and location help a lot) and why you’re here. Include a question or two about anything you want. New users who follow these simple steps will be sent a $25 gift certificate usually within 24 hours. It’s good on any size order at SmartMones.com.”
I’ll be waiting.
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Disclosure: I’ve edited your thread title from “Hello! New To all Male/46/PA” to “Hello! Looking for Pheromones to Help ReSpark My Marriage. M/46/PA” for topic clarity and forum readability. It’ll also generate more “reads” to your thread. If you want to opt-out simply let me know. Thank you!